As for the transitional titles (and don't forget you also get 10 captions); they are great to use when there is a change of scene. So, something like this:
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Movie title
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wedding planning clips (if you have them) - with caption
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rehearsal (if you have it) - with caption
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big day - transitional title w location
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ceremony
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photos - caption
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cocktail hour/reception - transitional title w location
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reception - captions at the funny parts :)
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guest interviews
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honeymoon - transitional title w location
- honeymoon clips - captions w fave parts